Non-thermal magnetic deicing using two-dimensional chromium telluride

Two-dimensional (2D) chromium telluride Cr2Te3 exhibits strong ferromagnetic ordering with high coercivity at low temperatures and paramagnetic behavior when approaching room temperature. The spin states of monolayer Cr2Te3 show ferromagnetic ordering in the ground state. In situ Raman analysis reveals a reversible structure transformation and hence proves ferromagnetic to paramagnetic transition during low-temperature heating cycles (0-25 °C). The magnetic phase transition near room temperature in 2D Cr2Te3 prompted an exploratory study of these layered materials for energy application. We demonstrate that the low-temperature ferromagnetic behavior can be used to magnetically deice material surfaces using an external magnetic source, avoiding the use of harsh chemicals and high temperatures. The hydrophobic nature and dipole interactions of H2O molecules with the surface of the 2D Cr2Te3 coating aid in the condensation of ice droplets formed on the surfaces. First-principles calculations also confirm the observed crystal structure, surface interaction, and magnetic properties of 2D Cr2Te3 © 2024 Elsevier B.V., All rights reserved.

Авторы
Chowde Gowda C. 1 , Kartsev Alexey I. 2, 3, 4 , Tiwari Nishant 5 , Safronov Alexander Arkadyevich 3 , Pandey Prafull 6 , Roy Ajit K. 7 , Ajayan Pulickel Madhava 8 , Galvão Douglas S.Soares 9 , Sekhar Tiwary Chandra Sekhar 1, 5
Издательство
Royal Society of Chemistry
Номер выпуска
46
Язык
English
Страницы
18691-18703
Статус
Published
Том
12
Год
2024
Организации
  • 1 School of Nano Science and Technology, Indian Institute of Technology Kharagpur, Kharagpur, India
  • 2 Bauman Moscow State Technical University, Moscow, Russian Federation
  • 3 MIREA - Russian Technological University (RTU MIREA), Moscow, Russian Federation
  • 4 RUDN University, Moscow, Russian Federation
  • 5 Department of Metallurgy and Material Engineering, Indian Institute of Technology Kharagpur, Kharagpur, India
  • 6 Materials Engineering, Indian Institute of Technology Gandhinagar, Gandhinagar, India
  • 7 Materials and Manufacturing Directorate, Air Force Research Laboratory, Dayton, United States
  • 8 George R. Brown School of Engineering and Computing, Houston, United States
  • 9 Department of Applied Physics and Center for Computational Engineering and Sciences, Universidade Estadual de Campinas, Campinas, Brazil
Ключевые слова
Coercive force; Ferromagnetic materials; Layered semiconductors; Paramagnetic materials; Paramagnetism; Single crystals; Chromium tellurides; Ferromagnetic orderings; High-coercivity; Low temperature behavior; Nonthermal; Paramagnetic behavior; Raman analysis; Situ Raman; Spin state; Two-dimensional; Ferromagnetism
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