Exposure to ambient particulate matter (PM) is one of the leading health risks globally. Several European regions experience high PM concentrations due to the burning of fossil fuels for domestic heating. Accordingly, Serbia ranks among the countries with the highest levels of air pollution. The annual mean concentrations are the most common indicator in exposure studies. However, this study uses station data in Serbia to indicate the concentrations to which the population is exposed during the heating season (October–April) based on daily PM