Synthesis of novel fluorescent 12a-aryl substituted indoxylisoquinolines via aryne-induced domino process

A novel effective protocol towards indolo[2,1-a]isoquinolinones via aryne-induced migration of aryl-anion in aryloxy substituted 3,4-dihydroisoquinolines is reported. These novel 12a-aryl substituted indoxylisoquinolines exhibit fluorescence properties and are characterized by green-shifted spectra and moderate quantum yields. © The Royal Society of Chemistry 2016.

Авторы
Varlamov A.V. 1 , Guranova N.I. 1 , Novikov R.A. 2 , Ilyushenkova V.V. 1 , Khrustalev V.N. 1 , Baleeva N.S. 3 , Borisova T.N. 1 , Voskressensky L.G. 1
Journal
RSC Advances
Номер выпуска
15
Язык
English
Страницы
12642-12646
Статус
Published
Ссылка
Внешняя ссылка
DOI
10.1039/C5RA25323C
Том
6
Год
2016
Организации
  • 1 Organic Chemistry Department, Peoples' Friendship University of Russia, 6, Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 2 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47, Leninskij avenue, Moscow, 119991, Russian Federation
  • 3 Institute of Bioorganic Chemistry, Russian Academy of Sciences, 16/10, Miklukho-Maklaya St, Moscow, 117997, Russian Federation
Ключевые слова
Aryloxy; Domino process; Fluorescence properties; Isoquinolinones; Fluorescence
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