Heterogeneous bromination of alkenes using Bi(III) polybromide complexes as {Br2} source

A new polybromide Bi(iii) complex (PyH)3{[Bi2Br9](Br2)} was synthesized and characterized by XRD and other methods. This compound is able to act as a selective bromination agent towards various types of substituted alkenes. © 2016 The Royal Society of Chemistry.

Авторы
Adonin S.A. 2, 1 , Perekalin D.S. 3 , Gorokh I.D. 2 , Samsonenko D.G. 2, 1 , Sokolov M.N. 2, 1, 4 , Fedin V.P. 1, 2
Номер выпуска
66
Язык
English
Страницы
62011-62013
Статус
Published
Том
6
Год
2016
Организации
  • 1 Nikolaev Institute of Inorganic Chemistry, SB RAS, Lavrentieva St. 3, Novosibirsk, 630090, Russian Federation
  • 2 Novosibirsk State University, Pirogova St. 2, Novosibirsk, 630090, Russian Federation
  • 3 Peoples' Friendship University of Russia, Department of Organic Chemistry, Mikhlukho-Maklaya St. 6, Moscow, 117198, Russian Federation
  • 4 Kazan Federal University, Alexander Butlerov Institute of Chemistry, Lobachevskogo str. 1/29, Kazan, 420008, Russian Federation
Ключевые слова
Substituted alkene; Hydrocarbons
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