First cage-like pentanuclear Co(II)-silsesquioxane

A new pentanuclear "cylinder"-like cobalt(ii) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols. © The Royal Society of Chemistry 2016.

Авторы
Bilyachenko A.N. 1, 2 , Yalymov A.I. 1 , Levitsky M.M. 1 , Korlyukov A.A. 7, 1 , Es'kova M.A. 1 , Long J. 3 , Larionova J. 3 , Guari Y. 3 , Shul'pina L.S. 1 , Ikonnikov N.S. 1 , Trigub A.L. 4 , Zubavichus Y.V. 4 , Golub I.E. 1 , Shubina E.S. 1 , Shul'pin G.B. 6, 5
Journal
Dalton Transactions
Издательство
Royal Society of Chemistry
Номер выпуска
35
Язык
English
Страницы
13663-13666
Статус
Published
Ссылка
Внешняя ссылка
DOI
10.1039/C6DT02026G
Том
45
Год
2016
Организации
  • 1 A.N. Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilov str. 28, Moscow, Russian Federation
  • 2 People's Friendship University of Russia, Miklukho-Maklay Str. 6, Moscow, 117198, Russian Federation
  • 3 Institut Charles Gerhardt de Montpellier (ICGM), UMR5253, Equipe IMNO, Université de Montpellier, Site Triolet Place Eugène Bataillon, Montpellier Cedex 5, 34095, France
  • 4 National Research Center, Kurchatov Institute, pl. Akad. Kurchatova 1, Moscow, 123098, Russian Federation
  • 5 Semenov Institute of Chemical Physics of RAS, ul. Kosygina dom 4, Moscow, 119991, Russian Federation
  • 6 Plekhanov Russian University of Economics, Stremyannyi pereulok dom 36, Moscow, 117997, Russian Federation
  • 7 Pirogov Russian National Research Medical University, Moscow, 117997, Russian Federation
Ключевые слова
Catalytic oxidation; Cobalt compounds; Cage likes; Oxidation of alkanes; Pentanuclear; Phenylsilsesquioxane; Silsesquioxanes; Slow relaxations; Catalyst activity
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