Crystal structure and Hirshfeld surface analysis of 1-[6-bromo-2-(4-fluorophenyl)-1,2,3,4-tetrahydroquinolin-4-yl]pyrrolidin-2-one
In the title compound, C19H18BrFN2O, the pyrrolidine ring adopts an envelope conformation. In the crystal, molecules are linked by intermolecular N—H...O, C—H...O, C—H...F and C—H...Br hydrogen bonds, forming a three-dimensional network. In addition, C—H...π interactions connect molecules into ribbons along the b-axis direction, consolidating the molecular packing. The intermolecular interactions in the crystal structure were quantified and analysed using Hirshfeld surface analysis.
2 Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskiy prospect 31-4, Moscow 119071, Russian Federation
3 Azerbaijan Medical University, Scientific Research Centre (SRC), A. Kasumzade St. 14. AZ 1022, Baku, Azerbaijan
4 Western Caspian University, Istiqlaliyyat Street 31, AZ1001, Baku, Azerbaijan
5 Department of Chemistry, Baku State University, Z. Xalilov Str, Az 1148 Baku, Azerbaijan
6 Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Türkiye
7 Department of Chemistry, M.M.A.M.C (Tribhuvan University) Biratnagar, Nepal