Photoredox-Catalyzed Hydrosulfonylation of Arylallenes

(Het)Arylallenes undergo hydrosulfonylation under photoredox-catalyzed conditions. The reaction gives vinyl sulfones in a regio- and diastereoselective manner, employing sodium sulfinates as the sulfonyl source and eosin Y as the photocatalyst. Indol-1-yl, pyrrol-1-yl, phenyl, and naphtylallenes might be used. Aliphatic allenes are incompatible with the reaction conditions. Copyright © 2019 American Chemical Society.

Авторы
Storozhenko O.A. 1 , Festa A.A. 1 , Detistova G.I. 1 , Rybakov V.B. 2 , Varlamov A.V. 1 , Van Der Eycken E.V. , Voskressensky L.G. 1
Журнал
Journal of Organic Chemistry
Язык
Английский
Статус
Опубликовано
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DOI
10.1021/ACS.JOC.9B02960
Год
2020
Организации
  • 1 Organic Chemistry Department, Science Faculty, Peoples' Friendship University of Russia, RUDN University, Miklukho-Maklaya st., 6, Moscow, 117198, Russian Federation
  • 2 Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, 1-3, Moscow, 119991, Russian Federation
  • 3 Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven, KU Leuven, Celestijnenlaan 200F, Leuven, B-3001, Belgium
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