Effect of the synthesis conditions on the crystal, local, and electronic structures of Ce4+ 2xCe3+ 2−2xM2O7 + x (M = Zr, Hf)

The effect of synthesis conditions (type of cations, annealing temperature, reductive or oxidative atmosphere) on the chemical composition and structure of compounds formed in the MO2-CeO2/Ce2O3 systems (M = Zr, Hf) was studied by X-ray diffraction, X-ray absorption spectroscopy, Raman spectroscopy, and thermogravimetric analysis. The isothermal annealing of the precursors at temperatures below 1000°C in air gives Ce0.5M0.5O2 powders with fluorite type cubic structure (space group Fm3m). High-temperature annealing above 1000°C gives rise to additional tetragonal (space group P42/nmc) (for zirconates) or monoclinic (space group P21/a) (for hafnates) phases. The annealing in a hydrogen atmosphere affords the compounds Ce4+ 2xCe3+ 2−2xM2O7 + x with an intermediate oxidation state of cerium and the x value depending on both the reduction conditions and the pre-annealing parameters. Vacuum annealing at 1400°C considerably decreases the content of Ce(IV) in the samples and affords a pyrochlore structure (space group Fd3m) with predominating Ce(III) cations. © Pleiades Publishing, Ltd., 2018 and V.V. Popov, A.P. Menushenkov, R.M. Khubbutdinov, A.A. Yastrebtsev, A.S. Sharapov, Ya.V. Zubavichus, R.D. Svetogorov, A.L. Trigub, N.A. Tsarenko, L.A. Arzhatkina, V.V. Kurilkin.