Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic). © 2018 The Royal Society of Chemistry.

Авторы
Arzumanyan A.V. 1 , Goncharova I.K. 1 , Novikov R.A. 2 , Milenin S.A. 3 , Boldyrev K.L. 3 , Solyev P.N. 2 , Tkachev Y.V. 2 , Volodin A.D. 1 , Smol'yakov A.F. 4, 1 , Korlyukov A.A. 5, 1 , Muzafarov A.M. 3, 1
Журнал
Green Chemistry
Издательство
Royal Society of Chemistry
Номер выпуска
7
Язык
Английский
Страницы
1467-1471
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1039/C8GC00424B
Том
20
Год
2018
Организации
  • 1 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, 119991, Russian Federation
  • 2 Engelhardt Institute of Molecular Biology, Russian Academy of Sciences, 32 Vavilova St., Moscow, 119991, Russian Federation
  • 3 Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 Profsoyuznaya St., Moscow, 117393, Russian Federation
  • 4 Faculty of Science, RUDN University, 6 Miklukho-Maklaya St., Moscow, 117198, Russian Federation
  • 5 N.I. Pirogov Russian National Research Medical University, 1 Ostrovityanov St., Moscow, 117997, Russian Federation
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