Arylhydrazones of a-keto esters via methanolysis of dichlorodiazabutadienes: synthesis and structural study

Novel approach to methyl 2-aryl-2-(arylhydrazono)acetates via methanolysis of dichlorodiazabutadienes was developed. Hydrogen bonding in methyl Z-2-phenyl-2-(phenyl-hydrazono)acetate was explored by DFT calculations and topological analysis of the electron density distribution within the framework of Bader's theory (QTAIM method).

Авторы
Shikhaliyev N.G. 1 , Maharramov A.M. 1 , Suleymanova G.T. 1 , Babazade A.A. 1 , Nenajdenko V.G. 2 , Khrustalev V.N. 3, 4 , Novikov A.S. 5 , Tskhovrebov A.G. 6, 3
Журнал
Mendeleev Communications
Издательство
Royal Society of Chemistry
Номер выпуска
5
Язык
Английский
Страницы
677-679
Статус
Опубликовано
DOI
10.1016/J.MENCOM.2021.09.028
Том
31
Год
2021
Организации
  • 1 Baku State Univ, AZ-1148 Baku, Azerbaijan
  • 2 Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
  • 3 Peoples Friendship Univ Russia, RUDN Univ, Moscow 117198, Russia
  • 4 Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
  • 5 St Petersburg State Univ, St Petersburg 199034, Russia
  • 6 Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia
Ключевые слова
keto esters; hydrazones; hydrogen bonding; DFT; QTAIM; calculations
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