Synthesis and crystal structure of 7,7,10-trimethyl-7-silabenzo[a]anthrone

Skeletal isomerization of arylsilanes that occurs under conditions of catalytic dehydrocyclization and is accompanied by migration of the triorganosilyl group was additionally confirmed by dehydrocyclization of dimethyl(2,4-dimethylphenyl)(1-naphthyl)silane on chromium-containing oxide catalysts.

Авторы
Polosin V.M. 1 , Astakhov A.A. 2 , Ryashentseva M.A. 3 , Tafeenko V.A. 4
Журнал
Russian Chemical Bulletin
Номер выпуска
12
Язык
Английский
Страницы
2121-2123
Статус
Опубликовано
Ссылка
Внешняя ссылка
DOI
10.1007/BF02495265
Том
46
Год
1997
Организации
  • 1 Stt. Sci. Res. Inst. Reagents E., 3 Bogorodsky val, 107076 Moscow, Russian Federation
  • 2 Russ. People's Frendship University, 6 ul. Miklukho-Maklaya, 117198 Moscow, Russian Federation
  • 3 N. D. Zelinsky Inst. of Organ. Chem., Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation
  • 4 Department of Chemistry, M. V. Lomonosov Moscow Stt. Univ., Vorob'evy Gory, 119899 Moscow, Russian Federation
Ключевые слова
7,7,10-trimethyl-7-silabenzo[a]anthrone; Catalytic dehydrocyclization; X-ray structural analysis
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